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Complete Publications

David V. Dearden Publication List, 13 Apr 2007


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This page is based in part on work supported by the U.S. National Science Foundation under grant number 0615964, but opinions expressed herein are those of David V. Dearden and do not necessarily reflect those of NSF.

Publications, University of Texas at Arlington and Brigham

Young University Faculty Research

  1. "Gas-Phase Molecular Recognition:  Gas-Phase Crown Ether-Alkali Metal Ion Complexes and Their Reactions With Neutral Crowns."  Zhang, H.; Chu, I.-H.; Leming, S.; Dearden, D. V.  J. Am. Chem. Soc. 1991, 113, 7415-7417.

  2. "The Gas-Phase Macrocyclic Effect:  Reaction Rates for Crown Ethers and the Corresponding Glymes with Alkali Metal Cations."  Zhang, H.; Dearden, D. V. J. Am. Chem. Soc. 1992, 114, 2754-2755.

  3. "Macrocyclic Chemistry Without Solvents:  Gas Phase Reaction Rates."  Dearden, D. V.; Zhang, H.; Chu, I.-H.; Wong, P.; Chen, Q.  Pure App. Chem. 1993, 65, 423-428.

  4. "Chiral Host-Guest Recognition in an Ion-Molecule Reaction."  Chu, I.-H.; Dearden, D. V.; Bradshaw, J. S.; Huszthy, P.; Izatt, R. M. J. Am. Chem. Soc. 1993, 115, 4318-4320.

  5. "Macrocyclic Chemistry in the Gas Phase:  Intrinsic Cation Affinities and Complexation Rates for Alkali Metal Cation Complexes of Crown Ethers and Glymes."  Chu, I.-H.; Zhang, H.; Dearden, D. V.  J. Am. Chem. Soc. 1993, 115, 5736-5744.

  6. "Gas Phase Studies of Valinomycin-Alkali Metal Cation Complexes:  Attachment Rates and Cation Affinities."  Wong, P. S. H.; Antonio, B. J.; Dearden, D. V. J. Am. Soc. Mass Spectrom. 1994, 5, 632-637. 

  7. "Effects of Alkyl Substitution on the Multidentate Attachment of Alkali Metal Cations by Ligands in the Gas Phase:  Kinetics and Thermochemistry of Cation Binding by Isomers of Dicyclohexano-18-crown-6."  Chu, I.-H.; Dearden, D. V. J. Am. Chem. Soc. 1995, 117, 8197-8203.

  8. "Mass Spectrometry," Brodbelt, J. S.; Dearden, D. V. In Physical Methods in Supramolecular Chemistry; J. E. D. Davies, Ed.; Pergamon: Oxford, 1996; Vol. 8.; pp. 567-591.

  9. "Complexes of p-tert-butylcalix[4]arene with Mono- and Dipositive Cations in the Gas Phase," Wong, P. S. H.; Yu, X.; Dearden, D. V. Inorg. Chim. Acta 1996, 246, 1-7.

  10. "The Macrobicyclic Cryptate Effect in the Gas Phase," Chen, Q.; Cannell, K.; Nicoll, J.; Dearden, D. V. J. Am. Chem. Soc. 1996, 118, 6335-6344.

  11. "Host-Guest Molecular Recognition without Solvents."  Dearden, D. V. in Physical Supramolecular Chemistry, NATO Advanced Research Workshop Series, Echegoyen, L.; Kaifer, A., eds.; Kluwer:  Dordrecht, 1996; pp. 229-247. 

  12. "Gas Phase Salt Clusters from Electrosprayed Alkaline Earth Colloids," Pope, R. M.; Shen, N.; Nicoll, J.; Dejsupa, C.; Dearden, D. V. Int. J. Mass Spectrom. Ion Proc. 1997, 162, 107-119.

  13. "Intrinsic Contributions to Chiral Recognition:  Discrimination Between Enantiomeric Amines by Dimethyldiketopyridino-18-crown-6 in the Gas Phase," Dearden, D. V.; Dejsupa, C.; Liang, Y.; Bradshaw, J. S.; Izatt, R. M. J. Am. Chem. Soc. 1997, 119, 353-359. 

  14. "Relative Ammonium Affinities of 18-Crown-6 and the Isomers of Dicyclohexano-18-Crown-6," Dearden, D. V.; Chu, I.-H. J. Inclusion Phenom. Mol. Recognit. Chem. 1997, 29, 269-282.

  15. "Gas Phase Stripping of Alkali Cations from Biomolecules via Reaction with Crown Ethers."  Pope, R. M.; Shen, N.; Hofstadler, S. A.; Dearden, D. V. Int. J. Mass Spectrom. 1998, 175, 179-186.

  16. "Analysis of Enantiomeric Excess Using Mass Spectrometry:  Fast Atom Bombardment / Sector and Electrospray Ionization / Fourier Transform Mass Spectrometric Approaches," Liang, Y.; Bradshaw, J. S.; Izatt, R. M.; Pope, R. M.; Dearden, D. V. Int. J. Mass Spectrom. 1999, 185/186/187, 977-988.

  17. "Gas Phase Studies of AmmoniumÑCyclodextrin Compounds Using Fourier Transform Ion Cyclotron Resonance," Kellersberger, K. A.; Dejsupa, C.; Liang, Y.; Pope, R. M.; Dearden, D. V. Int. J. Mass Spectrom., 1999, 193, 181-195.

  18. "Fundamental Factors Controlling the Exchange of Multidentate Ligands: Displacement of 12-Crown-4 and Triglyme from Complexes with Divalent Alkaline Earth Cations," Shen, N.; Pope, R. M.; Dearden, D. V. Int. J. Mass Spectrom. 2000, 195-196, 639-652.

  19. "Reactions of Multidentate Ligands with Ligated Alkali Cation Complexes: Self-Exchange and ÔSandwichÕ Complex Formation Kinetics of Gas Phase Crown EtherÑAlkali Cation Complexes," Nicoll, J. B.; Dearden, D. V. Int. J. Mass Spectrom. 2001, 204, 171-183.

  20. "Study of Gas Phase Molecular Recognition Using Fourier Transform Ion Cyclotron Resonance Mass Spectrometry (FTICR/MS)," Dearden, D. V.; Liang, Y.; Nicoll, J. B.; Kellersberger, K. A. J. Mass Spectrom. 2001, 36, 989-997.

  21. "Encapsulation of N2, O2, Methanol, or Acetonitrile by Decamethylcucurbit[5]uril(NH4+)2 Complexes in the Gas Phase: Influence of the Guest on ÔLidÕ Tightness," Kellersberger, K. A.; Anderson, J. D.; Ward, S. M.; Krakowiak, K. E.; Dearden, D. V. J. Am. Chem. Soc. 2001, 123, 11316-11317.

  22. "The Thermodynamic Basis for Enantiodiscrimination: Gas Phase Measurement of the Enthalpy and Entropy of Chiral Amine Recognition by Dimethyldiketopyridino-18-crown-6," Liang, Y.; Bradshaw, J. S.; Dearden, D. V. J. Phys. Chem. A 2002, 106, 9665-9671.

  23. "Alkali Metal Binding Energies of Dibenzo-18-crown-6:  Experimental and Computational Results," Anderson, J. D.; Paulsen, E. S.; Dearden, D. V. Int. J. Mass Spectrom. 2003, 227, 63-76.

  24. "Alkali Metal Ion Chemistry," Anderson, J. D.; Dearden, D. V. In The Encyclopedia of Mass Spectrometry; P. B. Armentrout, Ed.; Elsevier: San Diego, 2003; Vol. 1 (Theory and Ion Chemistry); pp. 783-787.

  25. "Low Pressure Ion-Molecule Equilibrium," Kellersberger, K. A.; Dearden, D. V. In The Encyclopedia of Mass Spectrometry; P. B. Armentrout, Ed.; Elsevier: San Diego, 2003; Vol. 1 (Theory and Ion Chemistry); pp. 338-345.

  26. "Host-Guest Chemistry in the Gas Phase," Dearden, D. V. In The Encyclopedia of Mass Spectrometry; P. B. Armentrout, Ed.; Elsevier: San Diego, 2003; Vol. 1 (Theory and Ion Chemistry); pp. 763-770.

  27. "Cucurbit[6]uril Pseudorotaxanes: Distinctive Gas Phase Dissociation and Reactivity," Zhang, H.; Paulsen, E. S.; Walker, K. A.; Krakowiak, K. E.; Dearden, D. V. J. Am. Chem. Soc. 2003, 125, 9284-9285.

  28. "Incorporation of a Venturi Device in Electrospray Ionization," Zhou, L.; Yue, B.; Dearden, D. V.; Lee, E. D.; Rockwood, A. L.; Lee, M. L. Anal. Chem. 2003, 75, 5978-5983.

  29. "Isotopic Compositions and Exact Masses of Single Isotopic Peaks," Rockwood, A. L.; Van Orman, J. R.; Dearden, D. V. J. Am. Soc. Mass Spectrom. 2004, 15, 12-21.

  30. Moody, J. Ward; Lawler, M. Jeannette; Boerio-Goates, Juliana; Turley, R. Steven; Dearden, David V.; Kowallis, Bart J.; Joner, Micheal D. Physical Science Foundations; BYU Academic Publishing: Provo, UT; 2005.

  31. "Sonic Spray Ionization Mass Spectrometry: A Powerful Tool Used to Characterize Fragile Metal-Assembled Cages," Gardner, J. S.; Harrison, R. G.; Lamb, J. D.; Dearden, D. V. New J. Chem. 2006, 30, 1276-1282.

Papers in Preparation

  1. "Molecular Beads on a Charged Molecular String: α,ω-Alkyldiammonium Complexes of Cucurbit[6]uril in the Gas Phase," Zhang, H.; Ferrell, T. A.; Asplund, M. C.; Dearden, D. V. Int. J. Mass Spectrom., accepted and in press.

Publications, Undergraduate Research

  1. "Cation Fluxes from Binary Ag+-Mn+ Mixtures in a H2O-CHCl3-H2O Liquid Membrane System Containing a Series of Macrocyclic Ligand Carriers." Izatt, R. M.; Dearden, D. V.; Brown, P. R.; Bradshaw, J. S.; Lamb, J. D.; Christensen, J. J. J. Am. Chem. Soc. 1983, 105, 1785-1790.

  2. "Metal Separations Using Emulsion Liquid Membranes." Izatt, R. M.; Dearden, D. V.; McBride, D. W.; Oscarson, J. L.; Lamb, J. D.; Christensen, J. J. Sep. Sci. Technol. 1983, 18, 1113-1129.

  3. "Facilitated Transport from Ternary Cation Mixtures Through Water-Chloroform-Water Membrane Systems Containing Macrocyclic Ligands." Izatt, R. M.; Lamb, J. D.; Dearden, D. V.; Brown, P. R.; McBride, D. W.; Christensen, J. J. J. Membrane Sci. 1984, 20, 273-284.

  4. "Cation Selectivity in a Toluene Emulsion Membrane System." Izatt, R. M.; Dearden, D. V.; Witt, E. R.; McBride, D. W.; Christensen, J. J. Solvent Extraction and Ion Exchange 1984, 2, 459-477.

Publications, Graduate Research

  1. "Ionization Energetics and Unimolecular Isomerization and Decomposition Pathways of Gas-Phase Pentyl, Hexyl, and Heptyl Radicals by Photoelectron Spectroscopy." Dearden, D. V.; Beauchamp, J. L. J. Phys. Chem. 1985, 89, 5359-5365.

  2. "Fundamental Studies of the Energetics and Dynamics of Ligand Dissociation and Exchange Processes at Transition Metal Centers in the Gas Phase: Mn(CO)x+, x = 1-6." Dearden, D. V.; Kirchner, N. J.; van Koppen, P. A. M.; Hayashibara, K.; Bowers, M. T.; Beauchamp, J. L. J. Am. Chem. Soc. 1989, 111, 2401-2409.

  3. "C-H Bond Activation as the Initial Step in the Co+-Mediated Demethanation of Propane: The Critical Role of Angular Momentum at the Rate-Limiting Transition State." van Koppen, P. A. M.; Brodbelt-Lustig, J.; Bowers, M. T.; Dearden, D. V.; Beauchamp, J. L.; Fisher, E. R.; Armentrout, P. B. J. Am. Chem. Soc. 1990, 112, 5663-5665.

  4. "Organometallic Reaction Energetics from Product Kinetic Energy Release Distributions." van Koppen, P. A. M.; Bowers, M. T.; Beauchamp, J. L.; Dearden, D. V. In Bonding Energetics in Organometallic Compounds; Marks, T. J., Ed.; American Chemical Society: Washington, D.C. 1990; pp. 34-54.

  5. "Kinetic Energy Release Distributions as a Probe of Ligation Effects on Potential Energy Surfaces in Organometallic Reactions. The Reversible Dehydrogenation of Cycloalkenes by Fe+." Dearden, D. V.; Beauchamp, J. L.; van Koppen, P. A. M.; Bowers, M. T. J. Am. Chem. Soc. 1990, 112, 9372-9378.

  6. "Transition Metal Ion Mediated C-H and C-C Bond Activation of Alkanes: Dynamical Coupling Between Entrance and Exit Channel Transition States." van Koppen, P. A. M.; Brodbelt-Lustig, J.; Bowers, M. T.; Dearden, D. V.; Beauchamp, J. L.; Fisher, E. R.; Armentrout, P. B. J. Am. Chem. Soc. 1991, 113, 2359-2369.

Publications, Postdoctoral Research

  1. "New Rydberg States of Aluminum Monofluoride Observed by Resonance-Enhanced Multiphoton Ionization Spectroscopy." Dearden, D. V.; Johnson, R. D., III; Hudgens, J. W. J. Phys. Chem. 1991, 95, 4291-4296.

  2. "Spectroscopic and ab Initio Studies of Difluoromethyl Radicals and Cations." Dearden, D. V.; Hudgens, J. W.; Johnson, R. D. III; Tsai, B. P.; Kafafi, S. A. J. Phys. Chem. 1992, 96, 585-594.

  3. "Detection and Characterization of Gas-Phase GaCl Using Resonance Enhanced Multiphoton Ionization." Dearden, D. V.; Johnson, R. D., III; Hudgens, J. W. J. Chem. Phys. 1992, 97, 8880-8885.

  4. "Aluminum Monochloride Excited States Observed by Resonance Enhanced Multiphoton Ionization Spectroscopy." Dearden, D. V.; Johnson, R, D., III; Hudgens, J. W. J. Chem. Phys. 1993, 99, 7521-7528.

  5. "Detection and Characterization of Gas-Phase InCl Using Resonance Enhanced Multiphoton Ionization." Johnson, R. D., III; Dearden, D. V.; Hudgens, J. W. J. Chem. Phys. 1994, 100, 3422-3428.

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